SYNTHESIS OF 2-DODECANOYL-3,5-DIHYDROXY-2-CYCLOHEXEN-1-ONE

被引：12

作者：

OLIVER, JE ^{[1
]}

WATERS, RM ^{[1
]}

LUSBY, WR ^{[1
]}

机构：

[1] INSECT CHEM ECOL LAB,BELTSVILLE,MD 20705

来源：

TETRAHEDRON | 1990年 / 46卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)86678-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Dodecanoyl-3,5-dihydroxy-2-cyclohexen-1-one, identified from the setal exudate of immature andromeda lace bug nymphs, Stephanitis takeyai, was synthesized. Key steps involved construction of the cyclohexanedione ring containing a phenyldimethylsilyl substituent as a masked hydroxyl group, protection of the 1,3-dicarbonyl system as an isoxazole, oxidative desilylation, and reductive disassembly of the isoxazole. © 1990.

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页码：1125 / 1130

页数：6

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