REACTIVITY OF CYCLOPALLADATED COMPOUNDS .23. FORMAL C-C TRIPLE-BOND SPLITTING IN AN ORGANOPALLADIUM COMPOUND

被引：29

作者：

MAASSARANI, F

PFEFFER, M

LEBORGNE, G

机构：

[1] UNIV STRASBOURG 1,CHIM COORDINAT LAB,CNRS,URA 416,F-67070 STRASBOURG,FRANCE

[2] UNIV RENNES 1,CRISTALLOCHIM LAB,F-35042 RENNES,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 11期

关键词：

D O I：

10.1021/om00161a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cationic cyclopalladated compound derived from cyclometalated 2-benzylpyridine affords a heterocyclic compound containing a benzo[b]-quinolizinium unit upon reaction with ethyl 3-phenyl-propiolate through an overall C‒C triple-bond cleavage of the alkyne. © 1990, American Chemical Society. All rights reserved.

引用

页码：3003 / 3005

页数：3

共 9 条

[1]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[2]

LEBERRE A, 1973, B SOC CHIM FR, P647

[3] REACTION OF CYCLOPALLADATED COMPOUNDS .15. CONTROLLED SYNTHESIS OF HETEROCYCLIC-COMPOUNDS THROUGH RING ENLARGEMENT BY ALKYNE INSERTIONS INTO THE PD-C BONDS OF CYCLOPALLADATED AMINES FOLLOWED BY SUBSEQUENT RING-CLOSURE [J].