PENDENT ARM MACROCYCLIC COMPLEXES - CRYSTAL-STRUCTURES OF AL(TCTA) AND IN(TS-TACN)

被引：39

作者：

BOSSEK, U

HANKE, D

WIEGHARDT, K

NUBER, B

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,W-4630 BOCHUM,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87045-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of Al3+ and In3+ containing the pendent arm macrocycles 1,4,7-tris(acetato)-1,4,7-triazacyclononane (TCTA) and 1,4,7-tris(2-mercaptoethyl)-1,4,7-tri-azacyclononane (TS-TACN), respectively, have been synthesized and their crystal structures determined. Al(TCTA) contains an octahedral fac-N3O3 donor set, whereas In(TS-TACN) has an octahedral fac-N3S3 donor set. Average Al-O and In-S distances are 1.846 and 2.397 angstrom, respectively.

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页码：1 / 5

页数：5

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