C-13 NMR-SPECTRA OF SATURATED HETEROCYCLES .8. TETRAHYDROFURANS AND 1,3-DIOXOLANES

被引:70
作者
ELIEL, EL
RAO, VS
PIETRUSIEWICZ, KM
机构
[1] Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina
来源
ORGANIC MAGNETIC RESONANCE | 1979年 / 12卷 / 08期
关键词
D O I
10.1002/mrc.1270120805
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The 13C NMR spectra of 17 methyl‐ and ethyl‐substituted tetrahydrofurans and 58 alkyl‐ and aryl‐ substituted 1,3‐dioxolanes are reported. For the cases in which substituents recur, additive substituent parameters are calculated and compared with similar parameters in cyclopentanes and in 6‐membered rings. Considering the conformational flexibility of 5‐membered ring systems, additivity of the parameters is surprisingly good. Copyright © 1979 Heyden & Son Ltd.
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页码:461 / 466
页数:6
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