STEREOELECTRONIC FACTORS IN THE SYNTHESIS OF TETRAHYDROFURANS BY HYDROXYL PARTICIPATION IN PHENYLTHIO MIGRATION

被引：25

作者：

MCINTYRE, S ^{[1
]}

WARREN, S ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)97421-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The factors controlling the title reaction were investigated with two tethered hydroxyl nucleophiles and include preferential attack at the more highly substituted carbon atom, preferential formation of the more highly substituted five-membered ring, and preferential closure in the 5-exo-tet sense according to Baldwin's rules. © 1990.

引用

页码：3457 / 3460

页数：4

共 19 条

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