SYNTHESIS OF 2-DEOXY-BETA-C-PYRANOSIDES BY DIASTEREOSELECTIVE HYDROGEN-ATOM TRANSFER

被引:27
作者
CRICH, D
LIM, LBL
机构
[1] Department of Chemistry, London, WC1H 0AJ
关键词
D O I
10.1016/S0040-4039(00)98814-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2-Deoxy-β-C-pyranosides are synthesized by sequential treatment of methyl 3-deoxy-2-phenylsulphonyl-4,5,7-tri-O-benzyl-D-arabino-heptulosonate with lithium naphthalenide and an alkyl halide followed by saponification and reductive decar{ballot box}ylation. © 1990 Pergamon Press plc.
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页码:1897 / 1900
页数:4
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