SYNTHESIS AND PROPERTIES OF 3-SUBSTITUTED POLYPYRROLES

被引：13

作者：

KAERIYAMA, K ^{[1
]}

MASUDA, H ^{[1
]}

机构：

[1] IND RES INST,KANAZAWA KU,YOKOHAMA 236,JAPAN

来源：

SYNTHETIC METALS | 1991年 / 41卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)91089-S

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Films of polypyrrole(PPY), poly(3-methylpyrrole)(PMPY), poly(3-octylpyrrole)(POCPY), poly(3-propanoylpyrrole)(PPRNPY), and poly(3-phenylpyrrole)(PPHPY) were electrochemically prepared and their properties were compared. PPY was the most highly conducting and the stablest in a doped state. POCPY was soluble in common organic solvents. Its oxidation potential and interband transition energy were higher than that of PPY. Conductivity of PPRNPY was as low as 0.3 S/cm. Different from poly(3-phenyl-thiophene), the substitution with phenyl groups did not reduce oxidation potential and interband transition energy.

引用

页码：389 / 392

页数：4

共 6 条

[1] SOLUBLE, CONDUCTING POLYMERS FROM 3-SUBSTITUTED THIOPHENES AND PYRROLES [J].