SYNTHESIS AND PROPERTIES OF TRANSITION-METAL COMPLEXES OF 5,5-BIS(N-8-QUINOLYLCARBAMOYL)NONANE

被引：4

作者：

CHAMBRON, JC ^{[1
]}

HIRATANI, K ^{[1
]}

机构：

[1] IND PROD RES INST,1-1-4 HIGASHI,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 06期

关键词：

D O I：

10.1039/dt9910001483

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several metal complexes of 5,5-bis(N-8-quinolylcarbamoyl)nonane (H2L1) and the copper(II) complex of 5,5-bis(N-2-methyl-8-quinolylcarbamoyl)nonane (H2L2) have been synthesised and their spectroscopic properties studied. Whereas complexes of Cu, Ni, Pd, Zn and Cd with H2L1 were obtained, no complex with Co and Pt could be isolated. On the other hand, the copper complex of H2L2 was readily obtained, but the nickel complex could not be isolated. These compounds can be formulated as [ML] in which the amide groups of H2L1 and H2L2 are fully deprotonated. They were characterized by mass, IR and H-1 NMR spectroscopy. Their ultraviolet-visible, luminescence and redox properties were also investigated.

引用

页码：1483 / 1486

页数：4

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