SYNTHESIS, STRUCTURE AND PRELIMINARY COMPLEXATION BEHAVIOR OF MACROCYCLIC THIOUREAS AND UREAS

被引：16

作者：

ROSSER, M

PARKER, D

FERGUSON, G

GALLAGHER, JF

HOWARD, JAK

YUFIT, DS

机构：

[1] UNIV DURHAM,DEPT CHEM,SOUTH RD,DURHAM DH1 3LE,ENGLAND

[2] UNIV GUELPH,DEPT CHEM,GUELPH N1G 2W1,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期

关键词：

D O I：

10.1039/c39930001267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.

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页码：1267 / 1269

页数：3

相关论文

共 13 条

[1]

Allen C. F. H., 1955, ORG SYNTH, VCV3, P394

[2] SPHERANDS CONTAINING CYCLIC UREA UNITS [J].

BRYANT, JA ;

HO, SP ;

KNOBLER, CB ;

CRAM, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (15) :5837-5843

[3] SYNTHESIS OF 1,10-DITHIA-4,7,13,16-TETRA-AZACYCLO-OCTADECANE, 1-AZA-4,7-DITHIACYCLONONANE, AND N,N'-1,2-BIS(1-AZA-4,7-DITHIACYCLONONYL)ETHANE - STRUCTURAL AND SOLUTION STUDIES OF THEIR SILVER COMPLEXES [J].

CRAIG, AS ;

KATAKY, R ;

MATTHEWS, RC ;

PARKER, D ;

FERGUSON, G ;

LOUGH, A ;

ADAMS, H ;

BAILEY, N ;

SCHNEIDER, H .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (09) :1523-1531

[4] SPHERAND HOSTS CONTAINING CYCLIC UREA UNITS [J].

CRAM, DJ ;

DICKER, IB ;

KNOBLER, CB ;

TRUEBLOOD, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) :6828-6830

[5] HOST GUEST COMPLEXATION .32. SPHERANDS COMPOSED OF CYCLIC UREA AND ANISYL UNITS [J].

CRAM, DJ ;

DICKER, IB ;

LAUER, M ;

KNOBLER, CB ;

TRUEBLOOD, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (23) :7150-7167

[6] BIFUNCTIONAL CHIRAL AUXILIARIES .2. THE SYNTHESIS OF 1,3-DIACYLIMIDAZOLIDIN-2-ONES FROM 1,2-DIAMINES [J].

DAVIES, SG ;

MORTLOCK, AA .

TETRAHEDRON LETTERS, 1991, 32 (36) :4791-4794

[7]

HTAY MH, 1976, TETRAHEDRON LETT, V79, P469

[8] MACROCYCLIC LIGANDS EXAMINED BY FAST ATOM BOMBARDMENT MASS-SPECTROMETRY - DIRECT OBSERVATION OF METAL CATION SELECTIVITY IN COMPLEXATION [J].

JOHNSTONE, RAW ;

ROSE, ME .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) :1268-1270

[9] BIS(ETHYLENETHIOUREA)GOLD(I) CHLORIDE HYDRATE [J].

JONES, PG ;

GUY, JJ ;

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (DEC15) :3321-3322

[10] SYNTHESIS AND BINDING-PROPERTIES OF AMIDE-FUNCTIONALIZED POLYAZA MACROCYCLES [J].

KATAKY, R ;

MATTHES, KE ;

NICHOLSON, PE ;

PARKER, D ;

BUSCHMANN, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (08) :1425-1432