VARIABLE TEMPERATURE STUDIES ON LUMINESCENCE FROM BENZIL IN A POLYMETHYLMETHACRYLATE GLASS - EXAMPLE OF MATRIX CONTROLLED PHOTOROTAMERISM

被引:29
作者
FANG, TS
SINGER, LA
机构
[1] Department of Chemistry, University of Southern California, Los Angeles
关键词
D O I
10.1016/0009-2614(78)85724-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dual fluorescence and phosphorescence at λm = 440 (F″), 500 (F′), 525 (P″) and 565 (P″) nm are noted from benzil in a polymethylmethacrylate glass between 77 and 300 K which are assigned to matrix imposed near-skewed (F″ and P″) and trans-planar (F′ andP′) geometries. © 1978.
引用
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页码:117 / 121
页数:5
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