SONOCHEMISTRY OF EPOXYALKYLHALIDES IN THE PRESENCE OF A ZINC COPPER COUPLE

被引：22

作者：

SARANDESES, LA

MOURINO, A

LUCHE, JL

机构：

[1] UNIV JOSEPH FOURIER,ETUD DYNAM & STRUCT SELECT LAB,BP 53X,F-38041 GRENOBLE,FRANCE

[2] UNIV SANTIAGO,DEPT QUIM ORGAN,E-15706 SANTIAGO,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000798

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under sonication in aqueous ethanol, a zinc-copper couple induces the conjugated addition of epoxyalkyl groups to electron deficient alkenes in synthetically useful yields, provided that the two reducible functionalities are sufficiently far apart; 3,4-epoxyalkylhalides have been found to form cyclopropane adducts.

引用

页码：798 / 799

页数：2

共 13 条

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