A FACILE AND STEREOSELECTIVE SYNTHESIS OF DIENEDIONES AND 6-OXO-2,4-DIENOIC ESTERS

被引：13

作者：

GUO, C ^{[1
]}

LU, XY ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 25期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0040-4039(00)92529-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ostopanic acid and ethyl 6-oxodocosa-2,4-dienoate were synthesized by a short route based on the palladium catalyzed isomerization of ynone and ynoic ester, respectively, using pent-4-ynal as a starting material.

引用

页码：3659 / 3662

页数：4

共 20 条

[1] CONJUGATED POLYENE SYNTHESIS VIA DISILYL DERIVATIVES - A DIRECT ACCESS TO OSTOPANIC ACID, A PLANT ANTICANCER AGENT, AND TO (6E)-LTB3 LEUKOTRIENE
BABUDRI, F
FIANDANESE, V
NASO, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (21) : 6245 - 6248
[2] AN EFFICIENT SYNTHESIS OF 13(S)-HYDROXY-9Z,11E-OCTADECADIENOIC (CORIOLIC) ACID
BLOCH, R
PERFETTI, MT
[J]. TETRAHEDRON LETTERS, 1990, 31 (18) : 2577 - 2580
[3] POLYACETYLENIC COMPOUNDS .240. CONSTITUENTS OF SERRATULA-WOLFII ANDRAE
BOHLMANN, F
CZERSON, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (06): : 2291 - 2295
[4] IDENTIFICATION OF 2 CONJUGATED PENTAENOIC ACIDS IN INSECT FAT, AJE
CASON, J
DAVIS, R
SHEEHAN, MH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (18) : 2621 - &
[5] POTENTIAL ALARM PHEROMONES FROM THE MEDITERRANEAN OPISTHOBRANCH SCAPHANDER-LIGNARIUS
CIMINO, G
SPINELLA, A
SODANO, G
[J]. TETRAHEDRON LETTERS, 1989, 30 (37) : 5003 - 5004
[6] FUNCTIONALIZED VINYLIC ORGANOLITHIUM COMPOUNDS, SYNTHETIC EQUIVALENT OF OMEGA-LITHIO SORBALDEHYDE
DUHAMEL, L
PLE, G
RAMONDENC, Y
[J]. TETRAHEDRON LETTERS, 1989, 30 (52) : 7377 - 7380
[7] GUO C, IN PRESS TETRAHEDRON
[8] PLANT ANTICANCER AGENTS .43. (E,E)-7, 12-DIOXO-OCTADECA-8, 10-DIEN-1-OIC ACID (OSTOPANIC ACID), A CYTOTOXIC FATTY-ACID FROM OSTODES-PANICULATA
HAMBURGER, M
HANDA, SS
CORDELL, GA
KINGHORN, AD
FARNSWORTH, NR
[J]. JOURNAL OF NATURAL PRODUCTS, 1987, 50 (02): : 281 - 283
[9] STRUCTURE ELUCIDATION OF A POTENT MUTAGEN FROM HUMAN FECES
HIRAI, N
KINGSTON, DGI
VANTASSELL, RL
WILKINS, TD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (22) : 6149 - 6150
[10] NEW FUNCTIONALIZED HORNER-WADSWORTH-EMMONS REAGENTS - USEFUL BUILDING-BLOCKS IN THE SYNTHESIS OF POLYUNSATURATED ALDEHYDES - A SHORT SYNTHESIS OF (+/-)-(E,E)-CORIOLIC ACID
KANN, N
REIN, T
AKERMARK, B
HELQUIST, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (19) : 5312 - 5323

← 1 2 →