ATOMIC STRUCTURES OF 2 RHOMBOHEDRAL FERROELECTRIC PHASES IN PB(ZR,TI)O3 SOLID SOLUTION SERIES

被引:144
作者
MICHEL, C
MOREAU, JM
ACHENBACH, GD
GERSON, R
JAMES, WJ
机构
[1] Departments of Physics and Chemistry, Graduate Center for Materials Research, University of Missouri-Rolla, Rolla, MO
关键词
D O I
10.1016/0038-1098(69)90429-3
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The atomic positions in perovskitic PbZrxTi1-xO3 were determined for x = 0.9 and x = 0.58, using X-ray and neutron diffraction. The space group is R3c for x = 0.9, the unit cell containing two formula units of the compound, and R3m for x = 0.58, the unit cell containing one formula unit. A linear relationship is found between the displacements of the two cations in isomorphous ferroelectric of the R3c space group. © 1969.
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页码:865 / +
页数:1
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