REACTIONS OF ORGANIC PEROXIDES .11. AMINO-PEROXIDES FROM CYCLIC KETONES

被引:21
作者
HAWKINS, EGE
机构
[1] BP Chemicals Ltd., Research and Development Department, Epsom Division, Epsom
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期
关键词
D O I
10.1039/j39690002671
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
It has been found that reaction of various cyclic ketones (cyclopentanone, 2-methyl-, 3-methyl-, 4-methyl- and 3,3,5-trimethylcyclohexanone and oycloheptanone) with hydrogen peroxide and ammonia produces the corresponding 1,1′-peroxydicycloalkylamine and, in some cases, the 1- hydroperoxycycloalkylamine. From cyclododecanone only the hydroperoxy-amine was obtained, whereas isophorone gave, in addition to its epoxide, both 2,3-epoxy-1-hydroperoxy-3,5,5-trimethylcyclohexylamine and 1,1′- peroxybis(2,3-epoxy-3,5,5-trimethylcyclohexyl)amine. The reactions of these peroxides studied included: (i) the formation of unsymmetrical peroxyamines from 1-hydroperoxy-3,3,5-trimethylcyclohexylamine and carbonyl compounds, and (ii) thermal and base-catalysed decomposition of some of the peroxy-amines, both symmetrical and unsymmetrical.
引用
收藏
页码:2671 / &
相关论文
共 3 条
[1]   REACTIONS OF ORGANIC PEROXIDES .X. AMINO-PEROXIDES FROM CYCLOHEXANONE [J].
HAWKINS, EGE .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (19) :2663-&
[2]   REACTIONS OF ORGANIC PEROXIDES .12. AMINO-PEROXIDES FROM ACYCLIC CARBONYL COMPOUNDS [J].
HAWKINS, EGE .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (19) :2678-&
[3]   THE BASE CATALYZED DECOMPOSITION OF A DIALKYL PEROXIDE [J].
KORNBLUM, N ;
DELAMARE, HE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (02) :880-881