STATIC SCATTERING FROM MULTICOMPONENT POLYMER SYSTEMS - THEORETICAL-MODELS

被引：52

作者：

VILGIS, TA ^{[1
]}

BENMOUNA, M ^{[1
]}

BENOIT, H ^{[1
]}

机构：

[1] INST CHARLES SADRON,F-67083 STRASBOURG,FRANCE

来源：

MACROMOLECULES | 1991年 / 24卷 / 16期

关键词：

D O I：

10.1021/ma00016a001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper deals with the generalization of the standard equation for scattering, 1/S(q) = 1/S0(q) + V, to multicomponent polymer systems and shows that the same result holds if it is written in matrix form. Three different methods are used: the Ornstein-Zernike formalism, the Random-Phase Approximation, and the Edwards Hamiltonian method. We compare these three methods in order to see how they work for multicomponent polymer systems. As a side result, we rederive the Flory-Huggins free energy without using a lattice model, and we generalize this to take into account Gaussian fluctuations in multicomponent systems.

引用

页码：4481 / 4488

页数：8

共 23 条

[1] A CLOSED-FORM, FREE-ENERGY FUNCTIONAL FOR A BINARY POLYMER MIXTURE [J].