SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF DIPHENYLDITHIOPHOSPHINATES OF METHYLMERCURY(II) AND PHENYLMERCURY(II) - CRYSTAL-STRUCTURE OF MEHGS2PPH2

被引：30

作者：

ZUKERMANSCHPECTOR, J ^{[1
]}

VAZQUEZLOPEZ, EM ^{[1
]}

SANCHEZ, A ^{[1
]}

CASAS, JS ^{[1
]}

SORDO, J ^{[1
]}

机构：

[1] UNIV SANTIAGO COMPOSTELA,FAC FARM,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83157-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methyl- and phenyl-mercury(II) derivatives of diphenyldithiophosphinic acid (HS2PPh2) have been prepared. The structure of crystalline MeHgS2PPh2 has been determined by X-ray diffraction and shown to consists of MeHgS2PPh2 molecules in which the mercury atom is bound to the methyl group and to one sulphur atom of the ligand, with a further weak intermolecular interaction (secondary bond) with the other sulphur atom of a neighbouring ligand holding the molecules in pairs in the lattice. The spectroscopic properties of RHgS2PPh2 (IR, Raman and H-1, C-13, P-31 and Hg119 NMR) are discussed in the light of the X-ray results.

引用

页码：67 / 74

页数：8

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