PREPARATION, STRUCTURE, AND SOME REACTIONS OF THE EVASIVE AZOBENZENE COMPLEX [FE2(CO)6(MU-PH2N2)]

被引：29

作者：

HANSERT, B ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERTSTR 21,D-79104 FREIBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 459卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)86079-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Fe2(CO)6(mu-Ph2N2)] (1) Was obtained in a two-step sequence from Fe2(CO)9 and phenyl azide via the intermediate tetraazadiene complex (CO)3Fe . Ph2N4 (2b). Its N-N bond length (1.41 angstrom) is 0.04 angstrom longer than that in [Fe2(CO)6(mu-Et2N2)] corresponding to an enhanced reactivity. Accordingly, the reactions of 1 with CO and H-2 which lead to [Fe2(CO)6(mu-PhN-CO-NPh)] (4) and [Fe2(CO)6(mu-NHPh)2] (5) respectively, involve cleavage of the N-N bond.

引用

页码：265 / 269

页数：5

共 31 条

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