ORGANOMETALLIC LANTHANOID COMPOUNDS .40. ETHER CLEAVAGE BY ORGANOLANTHANOIDS - ISOLATION AND X-RAY STRUCTURAL-ANALYSIS OF [(C5H5)2LU-(MU-O(CH2)4P(C6H5)2)]2 AND [(C5H5)2LU(OC4H8)]2(MU-O)

被引:90
作者
SCHUMANN, H
PALAMIDIS, E
LOEBEL, J
机构
关键词
D O I
10.1016/0022-328X(90)87133-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Cp2LuCH2SiMe3(THF) reacts with HPPh2 and HAsPh2 to give Cp2LuPPh2(THF) (2) and Cp2LuAsPh2(THF) (3) respectively. Crystallization of 2 yields [Cp2Lu(μ-O(CH2)4PPh2)] 2 (4) by THF cleavage, whereas 3 is hydrolyzed to give [Cp2Lu(THF)]2O (5). © 1990.
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页码:C49 / C52
页数:4
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