PHOTOCHEMICAL DEAZETATION OF 2,3-DIAZABICYCLO[2.2.2]OCT-2-ENE - PSEUDOROTATION OF THE CYCLOHEXANEDIYL BIRADICAL

被引：16

作者：

EDMUNDS, AJF ^{[1
]}

SAMUEL, CJ ^{[1
]}

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1989年 / 07期

关键词：

D O I：

10.1039/p19890001267

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：1267 / 1274

页数：8

共 59 条

[1] UV-LASER PHOTOCHEMISTRY OF THE AZOALKANE 2,3-DIAZABICYCLO[2.2.2]OCT-2-ENE - TRAPPING OF THE SHORT-LIVED, TRIPLET BIRADICAL 1,4-CYCLOHEXADIYL BY MOLECULAR-OXYGEN [J].

ADAM, W ;

HANNEMANN, K ;

WILSON, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (24) :7646-7647

[2] EVIDENCE FOR DIAZENYL DIRADICALS IN THE PHOTOISOMERIZATION OF 4-METHYLENE-3,3,5,5-TETRAMETHYLPYRAZOLINE [J].

ADAM, W ;

DORR, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (04) :1240-1241

[3] THERMOLYSIS AND PHOTOLYSIS OF THE AZOALKANE 4,5-DIAZA-7,8,8-TRIMETHYLTRICYCLO[4.2.1.03,7]NON-4-ENE - 1,3-DIRADICAL AND DIAZOALKANE FORMATION [J].

ADAM, W ;

GILLASPEY, WD ;

PETERS, EM ;

PETERS, K ;

ROSENTHAL, RJ ;

VONSCHNERING, HG .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (05) :580-586

[4] BICYCLIC AZOALKANES VIA URAZOLES DERIVED FROM CYCLOADDITION OF "N-PHENYL-1,2,4-TRIAZOLINE-3,5-DIONE WITH STRAINED BICYCLOALKENES [J].

ADAM, W ;

DELUCCHI, O ;

ERDEN, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (14) :4806-4809

[5] UV-LASER PHOTOCHEMISTRY OF THE AZOALKANE 1-PHENYL-2,3-DIAZABICYCLO[2.2.2]OCT-2-ENE - DETECTION AND LIFETIME DETERMINATION OF THE TRIPLET DIRADICAL 1-PHENYL-1,4-CYCLOHEXADIYL BY TIME-RESOLVED UV SPECTROSCOPY (FLASH-PHOTOLYSIS) AND BY TRAPPING WITH MOLECULAR-OXYGEN [J].

ADAM, W ;

GRABOWSKI, S ;

WILSON, RM ;

HANNEMANN, K ;

WIRZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (24) :7572-7573

[6] PHOTOCHEMISTRY OF THE AZOALKANES 2,3-DIAZABICYCLO[2.2.1]HEPT-2-ENE AND SPIRO[CYCLOPROPANE-1,7'-[2,3]DIAZABICYCLO[2.2.1]HEPT-2-ENE] - ON THE QUESTIONS OF ONE-BOND VS 2-BOND CLEAVAGE DURING THE DENITROGENATION, CYCLIZATION VS REARRANGEMENT OF THE 1,3-DIRADICALS, AND DOUBLE INVERSION [J].

ADAM, W ;

OPPENLANDER, T ;

ZANG, G .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (18) :3303-3312

[7] THERMAL AND PHOTODECOMPOSITION STUDIES WITH EXO- AND ENDO-5-METHOXY-2,3-DIAZABICYCLO[2.2.1]HEPT-2-ENE SYSTEM [J].

ALLRED, EL ;

SMITH, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (24) :6766-&

[8] NUCLEAR MAGNETIC RESONANCE LINE-SHAPE AND DOUBLE-RESONANCE STUDIES OF RING INVERSION IN CYCLOHEXANE-D11 [J].

ANET, FAL ;

BOURN, AJR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (04) :760-&

[9] ZUR REAKTION VON CYCLOHEXADIEN-(1.3) MIT AZODICARBONSAURE-DIATHYLESTER [J].

ASKANI, R .

CHEMISCHE BERICHTE-RECUEIL, 1965, 98 (08) :2551-&

[10]

BENZON MS, 1971, THESIS CORNELL U

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