SITE-SELECTIVE SPECTROSCOPY OF ND3+ IN LINBO3-ND AND LINBO3-ND, MG CRYSTALS

被引:54
作者
LIFANTE, G [1 ]
CUSSO, F [1 ]
JAQUE, F [1 ]
SANZGARCIA, JA [1 ]
MONTEIL, A [1 ]
VARREL, B [1 ]
BOULON, G [1 ]
GARCIASOLE, J [1 ]
机构
[1] UNIV LYON 1,CNRS,UA 442,F-69622 VILLEURBANNE,FRANCE
关键词
D O I
10.1016/0009-2614(91)90241-Z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Site-selection spectroscopy techniques have been used to investigate the different Nd3+ crystal-field sites appearing in LiNbO3:Nd3+ and LiNbO3:Nd3+, Mg2+ crystals. Singly doped crystals show the presence of two nonequivalent sites for Nd3+ (here labelled as Nd-1 and Nd-2 sites). Codoping the crystals with Mg2+ ions induces the presence of a new Nd3+ site (labelled as Nd-Mg site) concomitant with fewer Nd-1 sites. These three crystal-field sites have been optically characterized by their highest-energy emission peak of the 4F3 --> 4I9/2 transitions. The possible location for these sites is the host matrix is discussed.
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页码:482 / 488
页数:7
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