INTERACTION OF A POLYANION WITH AN OPPOSITELY CHARGED FLUOROCARBON HYDROCARBON SURFACTANT

被引：7

作者：

ESUMI, K ^{[1
]}

TAKEHANA, K ^{[1
]}

NOJIMA, T ^{[1
]}

MEGURO, K ^{[1
]}

机构：

[1] SCI UNIV TOKYO,INST COLLOID & INTERFACE SCI,SHINJUKU KU,TOKYO 162,JAPAN

来源：

COLLOIDS AND SURFACES | 1992年 / 64卷 / 01期

关键词：

ANIONIC POLYELECTROLYTE; CATIONIC SURFACTANT; COMPLEX; MICROPOLARITY; SOLUBILIZATION;

D O I：

10.1016/0166-6622(92)80157-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of poly(sodium 4-styrenesulfonate) (PSS) with the cationic surfactants hexadecyltrimethylammonium chloride (CTAC) and diethanol heptadecafluoro-2-undecanol methylammonium chloride (DEFUMAC), has been studied by surface tension, viscosity, fluorescence, and solubilization measurements. The anionic polymer can form complexes with CTAC or DEFUMAC. The complex ratio of the surfactant to PSS is lower for the PSS DEFUMAC system than for PSS CTAC, and complex formation of PSS-DEFUMAC is much more favorable than that of PSS CTAC. These complexes provide a hydrophobic environment, where the micropolarity of the PSS-DEFUMAC complex sensed by pyrene-1-carboxaldehyde is higher than that of PSS-CTAC, and the solubilization capacity of Yellow OB by the PSS-DEFUMAC complex is lower than that of PSS CTAC.

引用

页码：15 / 19

页数：5

共 19 条

[1] EXPLORATORY-STUDY OF THE EFFECT OF POLY-ELECTROLYTE SURFACTANT AGGREGATES ON PHOTOCHEMICAL BEHAVIOR
ABUIN, EB
SCAIANO, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (21) : 6274 - 6283
[2] FLUORESCENCE AND SOLUBILIZATION STUDIES OF POLYMER SURFACTANT SYSTEMS
ANANTHAPADMANABHAN, KP
LEUNG, PS
GODDARD, ED
[J]. COLLOIDS AND SURFACES, 1985, 13 (01): : 63 - 72
[3] CABANE B, 1985, COLLOID SURFACE, V13, P19, DOI 10.1016/0166-6622(85)80003-2
[4] FLUORESCENCE PROBE INVESTIGATION OF ANIONIC POLYMER CATIONIC SURFACTANT INTERACTIONS
CHANDAR, P
SOMASUNDARAN, P
TURRO, NJ
[J]. MACROMOLECULES, 1988, 21 (04) : 950 - 953
[5] CHU D, 1989, J AM CHEM SOC, V108, P6270
[6] INTERACTION OF IONIC SURFACTANTS WITH POLYMERS IN AQUEOUS-SOLUTION
GILANYI, T
WOLFRAM, E
[J]. COLLOIDS AND SURFACES, 1981, 3 (02): : 181 - 198
[7] POLYMER-SURFACTANT INTERACTIONS
GODDARD, ED
HANNAN, RB
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1977, 54 (12) : 561 - 566
[8] GOODARD ED, 1986, COLLOID SURFACE, V19, P255
[9] HAYAKAWA K, 1982, J PHYS CHEM-US, V86, P3866, DOI 10.1021/j100216a032
[10] SOLVENT-DEPENDENT FLUORESCENCE OF PYRENE-3-CARBOXALDEHYDE AND ITS APPLICATIONS IN ESTIMATION OF POLARITY AT MICELLE-WATER INTERFACES
KALYANASUNDARAM, K
THOMAS, JK
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (23) : 2176 - 2180

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