Solid state multinuclear NMR study of sigma-acetylide complexes of platinum, trans-[ClPt(P-n Bu-3)(2)-C C-p-C6H4-C C-Pt(P-n Bu-3)(2)Cl] and trans-[-Pt(P-n Bu-3)(2)-C C-p-C6H4-C C-](n)

被引：11

作者：

Duer, Melinda J. ^{[1
]}

Khan, Muhammad S. ^{[1
]}

Kakkar, Ashok K. ^{[1
]}

机构：

[1] Univ Chem Lab, Cambridge CB2 1EW, England

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1992年 / 1卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

platinum; polymer; shielding tensor; phosphorous; acetylide;

D O I：

10.1016/0926-2040(92)90005-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid state C-13, P-31 and Pt-195 NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric sigma-acetylide complexes of platinum, trans-[ClPt(P-n Bu-3)(2)-C C-p-C6H4-C C-Pt(P-n Bu-3)(2)Cl] and trans-[-Pt(P-n Bu-3)(2)-C C-p-C6H4-C C-](n). The Pt-195 shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

引用

页码：13 / 16

页数：4

共 17 条

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