MILLIMETER-WAVE ROTATIONAL SPECTRUM OF H2SIO

被引：38

作者：

BAILLEUX, S

BOGEY, M

DEMUYNCK, C

DESTOMBES, JL

WALTERS, A

机构：

[1] Université des Sciences et Technologies de Lille, Laboratoire de Spectroscopie Hertzienne, Associé au CNRS

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 04期

关键词：

D O I：

10.1063/1.467654

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first high resolution rotational spectrum of H2SiO in the gas phase has been obtained. This molecule was identified among several short-lived unknown species produced by a low power ''abnormal'' glow discharge in a mixture of SiH4, O-2, and Ar. On/off modulation of the discharge allowed lines belonging to each species to be characterized by their lifetime measured using a digitizing oscilloscope. In total 107 lines of H2SiO were measured between 140 and 470 GHz. Evidence for a possible large amplitude motion has been found from anomalies in the fit of close lying K-a doublers.

引用

页码：2729 / 2733

页数：5

共 28 条

[1] NONCLASSICAL DOUBLE-BRIDGED STRUCTURE IN SILICON-CONTAINING MOLECULES - EXPERIMENTAL-EVIDENCE IN SI2H2 FROM ITS SUBMILLIMETER-WAVE SPECTRUM [J].