PROPYLENE OLIGOMERIZATION OVER TI-AL-SILICALITE - EFFECT OF CATALYST PELLETING PRESSURE

被引：24

作者：

FORNI, L ^{[1
]}

PELOZZI, M ^{[1
]}

GIUSTI, A ^{[1
]}

FORNASARI, G ^{[1
]}

MILLINI, R ^{[1
]}

机构：

[1] ENIRICERCHE SPA,I-20097 SAN DONATO MILANE,ITALY

来源：

JOURNAL OF CATALYSIS | 1990年 / 122卷 / 01期

关键词：

D O I：

10.1016/0021-9517(90)90260-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nature of diffusion phenomena in TiAlsilicalite and ZSM-5 catalysts has been investigated by means of the GC pulse method. Bulk, Knudsen, and intracrystalline contributions to the overall diffusion resistance have been evaluated by employing benzene as a probe molecule. The analysis of these results, together with those coming from a more general physicochemical characterisation of the solid, provide insight into the effect of pelleting pressure on the structure of the catalyst. There are shown to be considerable changes in catalytic activity and aging behaviour in propylene oligomerisation as a function of pelleting pressure. © 1990.

引用

页码：44 / 54

页数：11

共 5 条

[1] SORPTION DIFFUSION IN MOLECULAR-SIEVES .2. AROMATICS IN Y AND ZSM-5 ZEOLITES [J].