PHOTOCATALYSIS AT ELEVATED PRESSURE - CHROMIUM HEXACARBONYL-CATALYZED HYDROGENATION OF NORBORNADIENE

被引:15
作者
MIRBACH, MJ [1 ]
STEINMETZ, D [1 ]
SAUS, A [1 ]
机构
[1] GESAMTHSCH DUISBURG,FACHBEREICH ANGEW CHEM 6,D-4100 DUISBURG,FED REP GER
关键词
D O I
10.1016/S0022-328X(00)92003-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The photo-catalysed hydrogenation of norbornadiene in the presence of chromium hexacarbonyl has been studied at pressures of up to 80 Bar. The norbornene/nortricyclene ratio increases considerably with increasing pressure; at and above 40 Bar both double bonds of norbornadiene are hydrogenated, to give norbornane. © 1979.
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页码:C13 / C15
页数:3
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