PREPARATION AND PROPERTIES OF DOUBLE-BRIDGED BEDT-TTF DIMER AND ITS PERCHLORATE SALT

被引：36

作者：

TACHIKAWA, T ^{[1
]}

IZUOKA, A ^{[1
]}

KUMAI, R ^{[1
]}

SUGAWARA, T ^{[1
]}

SUGAWARA, Y ^{[1
]}

机构：

[1] INST PHYS & CHEM RES,WAKO,SAITAMA 351,JAPAN

来源：

SOLID STATE COMMUNICATIONS | 1992年 / 82卷 / 01期

关键词：

D O I：

10.1016/0038-1098(92)90398-S

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A novel twin donor with double ethylene bridges (1) was synthesized and perchlorate salt of its cation radical was prepared. The salt showed a metallic temperature dependence of conductivity from room temperature down to about 100 K. In the salt the donor molecule takes a V-shape conformation and a donor packing shows a unique three dimensional arrangement. A bridging thia-crown moiety may play an important role in determining the conformation and the arrangement of the donor.

引用

页码：19 / 22

页数：4

共 15 条

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