THE REACTION OF [RU10C(CO)24][PPN]2 WITH CARBON-MONOXIDE TO YIELD [RU3(CO)12] AND [RU6C(CO)16]2-

被引:9
作者
COSTON, T
LEWIS, J
WILKINSON, D
JOHNSON, BFG
机构
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1016/0022-328X(91)86126-B
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The dianion [Ru10C(CO)24]2- in CH2Cl2 reacts with CO under ambient conditions to produce quantitative amounts of the species [Ru3(CO)12] and [Ru6C(CO)16]2-; the hydrido-anion [HRu10C(CO)24]- reacts similarly to form [Ru3(CO)12] and [HRu6C(CO)16]-.
引用
收藏
页码:C13 / C15
页数:3
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