A PALLADIUM-CATALYZED SYNTHESIS OF XYLYL ACETATES AND XYLYLENE DIACETATES

被引：20

作者：

BRYANT, DR

MCKEON, JE

REAM, BC

机构：

[1] Research and Development Department, Union Carbide Corporation, Chemicals and Plastics, South Charleston

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 04期

关键词：

D O I：

10.1021/jo01256a072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Xylenes and xylyl acetates are catalytically oxidized at moderate temperatures with a homogeneous palladiumstannous acetate catalyst and air (1 atm) in acetic acid. p-Xylene gives p-xylyl acetate, p-xylylene diacetate, and p-methylbenzylidene diacetate. The α,α′-/α,α-diacetate ratio is 31:1. The other xylenes give similar product mixtures. The selectivity of the diacetoxylation reaction is maintained when the pure xylyl acetates are oxidized under the same conditions. © 1969, American Chemical Society. All rights reserved.

引用

页码：1106 / &