THERMODYNAMIC INTERPRETATION OF SOLUTE-POLYMER INTERACTIONS AT INFINITE DILUTION

被引：10

作者：

KARIM, KA ^{[1
]}

BONNER, DC ^{[1
]}

机构：

[1] TEXAS TECH UNIV,DEPT CHEM ENGN,LUBBOCK,TX 79409

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1978年 / 22卷 / 05期

关键词：

D O I：

10.1002/app.1978.070220510

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Heats of solution at infinite dilution of solutes in poly(ethyl methacrylate) were estimated using gas–liquid chromatography over a temperature range of 417.74 K–427.55 K. The heat of solution is related to solute polarizability and dipole moment. Contributions of specific interactions such as hydrogen bonding and charge‐transfer complexing to the enthalpy of solution were also determined. Copyright © 1978 John Wiley & Sons, Inc.

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页码：1277 / 1290

页数：14

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