OPTICAL-SPECTRA OF LOCALIZED EXCESS ELECTRONS IN ALKALI-HALIDE CLUSTERS

被引:101
作者
RAJAGOPAL, G [1 ]
BARNETT, RN [1 ]
NITZAN, A [1 ]
LANDMAN, U [1 ]
HONEA, EC [1 ]
LABASTIE, P [1 ]
HOMER, ML [1 ]
WHETTEN, RL [1 ]
机构
[1] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024
关键词
D O I
10.1103/PhysRevLett.64.2933
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Excess electrons attached to small alkali halide clusters give rise to optical-absorption bands whose characteristics are highly specific to the mode of electron localization. Optical spectra measured by cluster beam and resonant two-photon ionization spectroscopy agree well with predictions of coupled classical-quantum simulations, and are interpreted in terms of two localization modes: surface F-center and diffuse surface states. © 1990 The American Physical Society.
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页码:2933 / 2936
页数:4
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