SELECTIVE SYNTHESIS OF OXYGENATES IN THE CO-H2 REACTION ON SUPPORTED RUTHENIUM CARBIDO-CLUSTER CATALYSTS

被引：17

作者：

IZUMI, Y

CHIHARA, T

YAMAZAKI, H

IWASAWA, Y

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

[2] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supported ruthenium carbido-cluster catalysts ([Ru6C(CO)16Me]-/oxide) selectively produced methanol, dimethyl ether, and formaldehyde in CO-H-2, in contrast to the preferential formation of methane and hydrocarbons on supported ruthenium cluster catalysts {[Ru6(CO)18]2-/oxide} without the interstitial carbon and conventional metallic Ru catalysts.

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页码：1395 / 1396

页数：2

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