FLUORIDE-ION IN GROUP-6 METAL-CARBONYL CHEMISTRY - AN UNEXPECTED PROMOTER OF CARBONYLATIVE INSERTIONS IN ORGANIC AND ORGANOMETALLIC ENYNES

被引：24

作者：

JORDI, L ^{[1
]}

SEGUNDO, A ^{[1
]}

CAMPS, F ^{[1
]}

RICART, S ^{[1
]}

MORETO, JM ^{[1
]}

机构：

[1] CSIC,CID,DEPT QUIM ORGAN BIOL,C JORDI GIRONA 18-26,E-08034 BARCELONA,SPAIN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1021/om00034a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ready carbonylative cycloadditions were observed in the protodesilylation of (((trimethylsilyl)alkynyl)(diallylamino)carbene)metal complexes mediated by fluoride ions. A study of the ability of this ion to activate the ''(CO)5M'' fragments for an efficient carbonylative insertion process was carried out and extended to organic enynes.

引用

页码：3795 / 3797

页数：3

共 17 条

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