ACTIVE-CENTER ASSOCIATION IN ANIONIC-POLYMERIZATION - ITS RELATION TO THE MECHANISM OF POLYMERIZATION OF DIENES IN NONPOLAR-SOLVENTS

被引：15

作者：

BYWATER, S

机构：

[1] National Research Council of Canada, Ottawa

来源：

POLYMER INTERNATIONAL | 1995年 / 38卷 / 04期

关键词：

ANIONIC POLYMERIZATION; DIENES; POLYMERIZATION MECHANISMS; ORGANOLITHIUM COMPOUNDS; NONPOLAR SOLVENTS; ACTIVE CENTER ASSOCIATION;

D O I：

10.1002/pi.1995.210380403

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The dissociation mechanism suggested for lithium-based polymerization in many cases requires a relationship between the degree of association of the active centres and the kinetic data. This connection has recently been questioned (R. N. Young, L. J. Fetters, J. S. Huang & R. Krishnamoorti, Polymer International, 33 (1994) 217). It is the purpose of the present communication to show that this questioning is not soundly based.

引用

页码：325 / 333

页数：9

共 36 条

[1] POLYMERIZATION KINETICS OF ISOPRENE INITIATED BY 1,1'-DIPHENYL-HEXYL-LITHIUM [J].

ALVARINO, JM ;

BELLO, A ;

GUZMAN, GM .

EUROPEAN POLYMER JOURNAL, 1972, 8 (01) :53-&

[2] STRUCTURE AND MECHANISM IN ANIONIC-POLYMERIZATION [J].

BYWATER, S .

PROGRESS IN POLYMER SCIENCE, 1994, 19 (02) :287-316

[3] STRUCTURE OF OLIGOMERIC POLYBUTADIENYLLITHIUM AND POLYBUTADIENE [J].

BYWATER, S ;

WORSFOLD, DJ ;

HOLLINGS.G .

MACROMOLECULES, 1972, 5 (04) :389-&

[4]

BYWATER S, 1960, CAN J CHEM, V38, P1891

[5]

BYWATER S, 1986, POLYM PREPR-ACS, V27, P140

[6]

BYWATER S, 1964, CAN J CHEM, V42, P2884

[7]

BYWATER S, 1987, RECENT ADV ANIONIC P, P109

[8]

BYWATER S, 1966, ADV CHEM SER, V52, P36

[9]

Bywater S., 1976, COMPREHENSIVE CHEM K, V15, P1

[10]

CRAMOND DN, 1966, EUR POLYM J, V2, P107

← 1 2 3 4 →