NUCLEAR MAGNETIC SHIELDING OF HYDRATED ALKALI AND HALIDE IONS IN AQUEOUS SOLUTION

被引：82

作者：

DEVERELL, C

机构：

[1] Division of Pure Chemistry, National Research Council of Canada

[2] Department of Physics, University of Kent, Canterbury

来源：

MOLECULAR PHYSICS | 1969年 / 16卷 / 05期

关键词：

D O I：

10.1080/00268976900100531

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various methods for the determination of the paramagnetic term of the shielding constant of alkali and halide ions in dilute aqueous solution are discussed. Values of the chemical shift of the hydrated ions, σpMaq and σpXaq, are obtained from solvent isotope chemical shifts of halide ions; spin relaxation rates of quadrupolar nuclei in dilute aqueous solution and from the concentration dependence of the chemical shift and relaxation rates of alkali and halogen nuclei in aqueous solutions of alkali halides. © 1969 Taylor and Francis Group, LLC.

引用

页码：491 / &

共 32 条

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[9] 19F NUCLEAR MAGNETIC RESONANCE CHEMICAL SHIFT OF ALKALI FLUORIDES IN LIGHT- AND HEAVY-WATER SOLUTIONS
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[10] DEVERELL C, TO BE PUBLISHED

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