NUCLEOPHILIC-SUBSTITUTION WITHIN THE PHOTOIONIZED VANDERWAALS COMPLEX C6H5CL-NH3

被引：36

作者：

MAEYAMA, T ^{[1
]}

MIKAMI, N ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 18期

关键词：

D O I：

10.1021/j100381a012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient generation of C6H5NH3+ was found after the selective ionization of the van der Waals complex C6H5Cl-NH3 which was prepared in a supersonic molecular beam. The action spectrum of the product and its appearance energy were observed by using the two-color mass-selected multiphoton ionization spectroscopy. From the energetics of the reaction it was concluded that the ion-molecule reaction is responsible for the process and the product is generated by the nucleophilic substitution reaction occurring within the photoionized van der Waals complex. © 1990 American Chemical Society.

引用

页码：6973 / 6977

页数：5

共 26 条

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