IRIDIUM OXIDE-BASED MICROELECTROCHEMICAL TRANSISTORS FOR PH SENSING

被引:56
作者
PASZTOR, K [1 ]
SEKIGUCHI, A [1 ]
SHIMO, N [1 ]
KITAMURA, N [1 ]
MASUHARA, H [1 ]
机构
[1] RES DEV CORP JAPAN, MICROPHOTOCONVERS PROJECT, SODEGAURA, CHIBA 29902, JAPAN
关键词
D O I
10.1016/0925-4005(93)80023-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A study on electrochemically deposited iridium oxide films on Au wire and a pair of Au microelectrodes is reported. The open-circuit potential of the deposited film on an Au wire has been studied by a series of measurements. The pH sensitivity of the film is shown to be -64 to -66 mV/pH, while the relevant extrapolated potential at pH = 0 ranges from 0.67 to 0.71 V. Iridium oxide-based microelectrochemical transistors have also been fabricated. The resistance of the film on a pair of Au microelectrodes changes by 1.5 orders of magnitude from 300 to 8 MOMEGA as the gate voltage is stepped from -0.3 to 0.3 V. The response time of the device for chemical stimulation is less than 40 s and the device is demonstrated to be applicable as a pH sensor.
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页码:225 / 230
页数:6
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