STUDIES ON ORGANOLANTHANIDE COMPLEXES .45. THE FORMATION AND X-RAY CRYSTAL-STRUCTURE OF BIS(2-METHOXYETHYLCYCLOPENTADIENYL)ERBIUM HYDROXIDE

被引：31

作者：

DENG, DL ^{[1
]}

SONG, FQ ^{[1
]}

WANG, ZY ^{[1
]}

QIAN, CT ^{[1
]}

WU, GA ^{[1
]}

ZHENG, PJ ^{[1
]}

机构：

[1] FUDAN UNIV,CTR ANAL & MEASUREMENT,SHANGHAI 200433,PEOPLES R CHINA

来源：

POLYHEDRON | 1992年 / 11卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)83591-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The partial hydrolysis of Cp'2ErCl (1) (Cp' = CH3OCH2Ch2C5H4) affords [CP'2Er(mu-OH)]2, the single crystal X-ray structure of which reveals that the complex is dimeric with bridging hydroxide groups. The molecular structure shows the hydroxyl groups bridging with distances Er-O = 2.258(5), 2.216(5) angstrom, and the methoxyethyl group coordinating with distances Er-O(1) = 2.542(3), Er-Cp1 = 2.3981(4) and Er-Cp2 = 2.1680(3) angstrom. The bond angles of O-Er-O* and O-Er-O(1) in 2 are 71.6(2) and 73.2 (2)-degrees, respectively.

引用

页码：2883 / 2887

页数：5

共 13 条

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