SYNTHESIS AND REACTIONS OF 2-CYCLOPROPYL-2-PROPENYLTRIMETHYLSILANE - SILICON-DIRECTED GENERATION OF CYCLOPROPYLCARBINYL SYSTEM

被引：9

作者：

HOJO, M ^{[1
]}

OHSUMI, K ^{[1
]}

HOSOMI, A ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)61105-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Cyclopropyl-2-propenyltrimethylsilane reacts with various kinds of carbon electrophiles to afford the corresponding allylation products without contamination of other products based on the rearrangement of a cyclopropyl ring.

引用

页码：5981 / 5982

页数：2

共 8 条

[1]

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[2]

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HOJO, M ;

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HOSOMI, A .

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[5]

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[6] THE CERIUM MEDIATED CONVERSION OF ESTERS TO ALLYLSILANES [J].

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[7] LONG-LIVED CYCLOPROPYLCARBINYL CATIONS [J].

OLAH, GA ;

REDDY, VP ;

PRAKASH, GKS .

CHEMICAL REVIEWS, 1992, 92 (01) :69-95

[8]

VOGEL P, 1985, CARBOCATION CHEM, P350

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