ABOUT HOT BANDS AND PAPE BANDS IN SPECTRA OF C3-UPSILON SYMMETRICAL-TOP MOLECULES

被引：39

作者：

GRANER, G

机构：

[1] Laboratoire de Physique Moléculaire Applications, C.N.R.S, Laboratoire associé aux Universités Pierre, Marie Curie et Université Paris-Sud, Université Paris-Sud, 91405 Orsay Cedex

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 161卷 / 01期

关键词：

D O I：

10.1006/jmsp.1993.1216

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The purpose of this paper is to present simple ideas about two kinds of infrared bands which are not considered in classical text books, namely hot bands and PAPE bands. The presentation is limited to molecules with C3v symmetry. PAPE bands are parallel bands with a perpendicular structure and belong to the A1 + A2 vibrational symmetry. Their different appearances are discussed. Hot bands are very simple when the lower state has an A1 vibrational symmetry. We concentrate on the case where it has an E-type symmetry. Many examples of actual bands are quoted. © 1993 Academic Press Inc.

引用

页码：58 / 79

页数：22

共 42 条

[1] SIMULTANEOUS ANALYSIS OF MID-INFRARED AND FAR-INFRARED PROPYNE LASER EMISSIONS [J].

ALADLOUNI, T ;

GRANER, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1988, 127 (01) :186-199

[2] GROUND-STATE CONSTANTS A(0), D(0)(K) AND H(0)(K) OF CH3CN [J].

ANTTILA, R ;

HORNEMAN, VM ;

KOIVUSAARI, M ;

PASO, R .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1993, 157 (01) :198-207

[3] ROVIBRATIONAL STUDY OF A PARALLEL BAND TO PERPENDICULAR STRUCTURE MU4+MU6 OF CH3BR [J].

BENSARIZ.N ;

ALAMICHEL, C ;

AMIOT, C .

MOLECULAR PHYSICS, 1974, 27 (06) :1491-1501

[4] ETUDE ROVIBRATIONNELLE DE LA BANDE PARALLELE A STRUCTURE PERPENDICULAIRE V4+V6 DE CH3 CL-35 [J].

BENSARIZIZI, N ;

ALAMICHEL, C .

MOLECULAR PHYSICS, 1981, 44 (05) :1109-1118

[5]

BENSARIZIZI N, 1973, THESIS ORSAY

[6] SPECTRAL INTENSITIES IN THE NU-3 BAND OF (CH3CL)-C-12-CL-37 [J].

BLANQUET, G ;

WALRAND, J ;

MAI, DN .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1989, 133 (02) :471-474

[7] VIBRATIONAL-SPECTRA AND FORCE-CONSTANTS OF SYMMETRIC TOPS - ROVIBRATIONAL ANALYSIS OF 2-NU-6 AND 2-NU-6-NU-6 OF (H3SICL)-CL-35 AND (H3SICL)-CL-37, AND A NEW METHOD FOR THE DETERMINATION OF AO AND DKO [J].

BURGER, H ;

SCHIPPEL, G ;

RUOFF, A ;

ESSIG, H ;

CRADOCK, S .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1984, 106 (02) :349-361

[8] VIBRATIONAL-SPECTRA AND FORCE-CONSTANTS OF SYMMETRIC TOPS .30. ROVIBRATIONAL SPECTRA OF CF3 CL-35 IN THE NU-5, NU-1+NU-5 AND NU-2+NU-5 REGION [J].

BURGER, H ;

GRASSOW, R ;

RUOFF, A .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1983, 39 (11) :985-992

[9] THE HIGH-RESOLUTION FOURIER-TRANSFORM INFRARED-SPECTRUM OF H3SIF NEAR 2200 CM-1 - ROVIBRATIONAL ANALYSIS OF THE FUNDAMENTALS NU-1 AND NU-4 AND THEIR PERTURBERS 3-NU-6+/-1 AND 3-NU-6+/-3 [J].

BURGER, H ;

SCHULZ, P .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 125 (01) :140-153

[10] VIBRATIONAL-SPECTRA AND FORCE-CONSTANTS OF SYMMETRIC TOPS .25. ROVIBRATIONAL SPECTRUM OF THE FUNDAMENTAL UPSILON-6 OF H3SII NEAR 600 CM-1 [J].

BURGER, H ;

RAHNER, A ;

SCHULZ, P ;

RUOFF, A ;

DEROCHE, JC .

MOLECULAR PHYSICS, 1982, 45 (03) :721-731

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