A COULOMB EXPLOSION MODEL APPLIED TO CHARGE SEPARATION IN NITROSYL HALIDE AND RELATED DICATIONS

被引：22

作者：

ELAND, JHD

SHEAHAN, JR

机构：

[1] Physical Chemistry Laboratory, Oxford, OX1 3QZ, South Parks Road

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 223卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(94)00477-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoelectron-photoion-photoion coincidence spectra of NOF, NOCl, NOBr and NOCF3 from ionisation of the parent molecules by 40.8 and 48.4 eV light are reported. The peak shapes arising from atomisation of the triatomic dications cannot be well fitted by reasonable models of intermediate diatomic fragment formation, and a Coulomb explosion model incorporating charge exchange is proposed to explain them.

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页码：531 / 536

页数：6

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