APPLICATION OF TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY TO CHEMICAL-KINETICS

被引：6

作者：

RIMAI, L

KAISER, EW

SCHWAB, E

LIM, EC

机构：

[1] Ford Motor Company, Dearborn, MI

[2] Chemistry Department, University of Akron, Akron, OH

来源：

APPLIED OPTICS | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1364/AO.31.000350

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We discuss the application of time-resolved infrared spectral photography to the determination of the time-dependent reactant and product concentrations in the simple chain reaction of chlorine atoms, generated by pulsed photolysis, with ethane-Cl2 mixtures. The technique and experimental results are discussed in terms of the limitations and advantages of the method for general kinetic studies in the microsecond and submicrosecond time domain.

引用

收藏

页码：350 / 357

页数：8

相关论文

共 23 条

[1] TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY - STUDY OF LASER-INITIATED EXPLOSIONS IN HN3 [J].

AVOURIS, P ;

BETHUNE, DS ;

LANKARD, JR ;

ORS, JA ;

SOROKIN, PP .

JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (04) :2304-2312

[2] EVALUATED KINETIC AND PHOTOCHEMICAL DATA FOR ATMOSPHERIC CHEMISTRY [J].

BAULCH, DL ;

COX, RA ;

HAMPSON, RF ;

KERR, JA ;

TROE, J ;

WATSON, RT .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1980, 9 (02) :295-471

[3] TIME-RESOLVED INFRARED STUDY OF BIMOLECULAR REACTIONS BETWEEN TERT-BUTYL RADICALS [J].

BETHUNE, DS ;

LANKARD, JR ;

SOROKIN, PP ;

SCHELLSOROKIN, AJ ;

PLECENIK, RM ;

AVOURIS, P .

JOURNAL OF CHEMICAL PHYSICS, 1981, 75 (05) :2231-2236

[4] TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY - NEW TECHNIQUE [J].

BETHUNE, DS ;

LANKARD, JR ;

LOY, MMT ;

SOROKIN, PP .

IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1979, 23 (05) :556-575

[5] TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY [J].

BETHUNE, DS ;

LANKARD, JR ;

SOROKIN, PP .

OPTICS LETTERS, 1979, 4 (04) :103-105

[6]

BETHUNE DS, 1983, ADV LASER SPECTROSC, V2, P1

[7]

BLOEMBERGEN N, 1965, NONLINEAR OPTICS, P14

[8] HCL VIBRATIONAL FUNDAMENTAL-BAND - LINE-INTENSITIES AND TEMPERATURE-DEPENDENCE OF SELF-BROADENING COEFFICIENTS [J].

CHACKERIAN, C ;

GOORVITCH, D ;

GIVER, LP .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1985, 113 (02) :373-387

[9] STIMULATED ELECTRONIC RAMAN-SCATTERING AS A TUNABLE INFRARED SOURCE [J].

COTTER, D ;

HANNA, DC ;

KARKKAINEN, PA ;

WYATT, R .

OPTICS COMMUNICATIONS, 1975, 15 (02) :143-146

[10] INTENSITIES IN THE NU-5, NU-7 AND NU-8+N-11 BANDS OF THE ETHANE (C2H6)-C-12 [J].

DANGNHU, M ;

PINE, AS ;

LAFFERTY, WJ .

CANADIAN JOURNAL OF PHYSICS, 1984, 62 (05) :512-519