LOSSEN-LIKE REARRANGEMENT OF N-[ALPHA-METHYLBENZYL(PHENYL)PHOSPHINOYL]-O-METHYLSULFONYLHYDROXYLAMINE WITH METHYLAMINE - RETENTION OF CONFIGURATION AT PHOSPHORUS AS REVEALED BY X-RAY CRYSTALLOGRAPHY

被引：3

作者：

FAWCETT, J ^{[1
]}

HARGER, MJP ^{[1
]}

SREEDHARANMENON, R ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The diastereoisomers of the title compound 6 rearrange with high stereospecificity on treatment with MeNH2, giving PhMeCHP(O)(NHMe)NHPh in which the migrating phenyl group has been replaced by MeNH2 with retention of configuration at phosphorus.

引用

页码：227 / 229

页数：3

共 8 条

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