A ZIRCONIUM CATALYZED SYNTHESIS OF 1,4-DIMAGNESIUM REAGENTS

被引：86

作者：

LEWIS, DP

MULLER, PM

WHITBY, RJ

JONES, RVH

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

[2] ICI FINE CHEM MFG ORG,GRANGEMOUTH FK3 8XG,STIRLING,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 46期

关键词：

ZIRCONIUM; GRIGNARD; CARBOMETALLATION; 1,4-DIMAGNESIUM; CATALYSIS;

D O I：

10.1016/S0040-4039(00)93606-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The zirconium catalysed addition of diethylmagnesium to a variety of unactivated alkenes affords either the simple carbometallation product, or 1,4-dimagnesium reagents depending on the conditions and substrate. The products can be successfully functionalised with a variety of electrophiles.

引用

页码：6797 / 6800

页数：4

共 8 条

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