CONDENSATION PRODUCTS FROM THE REACTIONS OF GLYOXAL WITH 2-SUBSTITUTED BENZYLAMINES - THE FORMATION AND CRYSTAL-STRUCTURES OF 2,2'-BI(1,2,3,4-TETRAHYDROQUINAZOLINE), AND 2,4,6,8,10,12-HEXAKIS(2-METHYLBENZYL)-2,4,6,8,10,12-HEXAAZAISOWURTZITANE

被引：11

作者：

BATSANOV, A

COLE, JC

CRAMPTON, MR

HAMID, J

HOWARD, JAK

MILLAR, R

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,DURHAM,ENGLAND

[2] DRA,SEVENOAKS TN14 7BP,KENT,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 03期

关键词：

D O I：

10.1039/p29940000421

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Condensation of glyoxal with 2-aminobenzylamine produces the novel compound 2,2'-bi(1,2,3,4-tetrahydroquinazoline), 6, the structure of which has been confirmed by X-ray crystallography. However, reaction of glyoxal with other 2-substituted benzylamines yields hexabenzylhexaazaisowurtzitanes. The crystal structure of the derivative prepared from 2-methylbenzylamine has been determined and is compared with that of the derivative from 4-chlorobenzylamine

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页码：421 / 424

页数：4

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