ALKOXIDES AND DOUBLE ALKOXIDES OF ZINC

被引：24

作者：

MEHROTRA, RC

ARORA, M

机构：

[1] University of Rajasthan, Chemical Laboratories, Jaipur

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1969年 / 370卷 / 5-6期

关键词：

D O I：

10.1002/zaac.19693700513

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc methoxide and isopropoxide were prepared by the reaction of zinc chloride with the appropriate lithium alkoxide and a few other alkoxides, Zn(OR)2 (where R = Et, Bun, But and C8H17n) have been synthesized by the alcoholysis of methoxide. All these alkoxides are non‐volatile and insoluble in alcohols and other organic solvents. The non‐formation of insoluble zinc ethoxide from zinc chloride by treating it with lithium ethoxide was found to be due to its complexing tendency with lithium chloride, giving soluble products of the type LixZn(OEt)2Clx. A few soluble double alkoxides of lithium and zinc have also been isolated. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：300 / &

共 16 条

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