SYNTHESIS, STRUCTURE, AND 2 D-NMR STUDIES OF NOVEL CHIRAL (ETA-3-ALLYL)PALLADIUM(II) COMPLEXES CONTAINING THE BIDENTATE LIGAND SPARTEINE

被引：73

作者：

TOGNI, A ^{[1
]}

RIHS, G ^{[1
]}

PREGOSIN, PS ^{[1
]}

AMMANN, C ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 03期

关键词：

D O I：

10.1002/hlca.19900730321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel cationic allylpalladium (II) comp, exes containing the alkaloid (−)sparteine (1) as a bidentate ligand have been prepared. Two of them, [η3(cyclohex‐2‐enyl)] (sparteine)palladium(II) hexafluorophosphate([Pd(η3‐C6 H9)(sparteine)][PF6] 3b) and (sparteine)[η3‐(1,1,3‐triphenylallyl)] palladium (II) trifluorophosphate ([Pd(η3‐Ph2CCHCHPh)(sparteine)][sparteine)] [CF3SO3]; (3c) were characterized by X‐ray diffraction. The application of 2D‐NMR methods (COSY and NOESY)affords a correlation between the solid‐state and solution structures for complex 3c. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：723 / 732

页数：10

共 42 条

[1] AKERMARK B, 1987, ORGANOMETALLICS, V6, P620
[2] ALBINATI A, UNPUB ORGANOMETALLIC
[3] TWO-DIMENSIONAL NMR-STUDIES OF PT(2-METHALLYL)(SNCL3)(STYRENE) - RECOGNITION AND INTERPRETATION OF SIMULTANEOUS EXCHANGE PROCESSES VIA H-1 NOESY
AMMANN, C
PREGOSIN, PS
RUEGGER, H
GRASSI, M
MUSCO, A
[J]. MAGNETIC RESONANCE IN CHEMISTRY, 1989, 27 (04) : 355 - 359
[4] ASYMMETRIC-SYNTHESIS - ASYMMETRIC CATALYTIC ALLYLATION USING PALLADIUM CHIRAL PHOSPHINE COMPLEXES
AUBURN, PR
MACKENZIE, PB
BOSNICH, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (07) : 2033 - 2046
[5] BECKER ED, 1980, HIGH RESOLUTION NMR, P73
[6] METAL-COMPLEXES OF 3 SPARTEINE DIASTEREOISOMERS - PROPERTIES AND REACTIVITIES OF COPPER(II) DERIVATIVES
BOSCHMANN, E
WEINSTOCK, LM
CARMACK, M
[J]. INORGANIC CHEMISTRY, 1974, 13 (06) : 1297 - 1300
[7] SYNTHESIS AND CHARACTERIZATION OF (-)-SPARTEINE METAL SALT COMPLEXES
BOSCHMANN, E
NYPAVER, GA
MAJORS, JP
EALY, SM
VANHORN, M
[J]. JOURNAL OF COORDINATION CHEMISTRY, 1978, 7 (03) : 141 - 147
[8] DYNAMIC BEHAVIOR AND X-RAY-ANALYSIS OF CHIRAL ETA-3-ALLYLPALLADIUM COMPLEXES .2.
CESAROTTI, E
GRASSI, M
PRATI, L
DEMARTIN, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) : 407 - 419
[9] ALLYLLITHIUM, ALLYLSODIUM, AND ALLYLMAGNESIUM HYDRIDE - GEOMETRIES AND BONDING - A COMPARATIVE ABINITIO STUDY
CLARK, T
ROHDE, C
SCHLEYER, PV
[J]. ORGANOMETALLICS, 1983, 2 (10) : 1344 - 1351
[10] COLLMAN JP, 1987, PRINCIPLES APPLICATI, pCH19

← 1 2 3 4 5 →