NEUTRAL ALKYLATION OF CHIRAL ALLYLIC CYCLIC CARBONATES CATALYZED BY PALLADIUM COMPLEX

被引：24

作者：

KANG, SK

KIM, SG

LEE, JS

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 09期

关键词：

D O I：

10.1016/S0957-4166(00)82096-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclic carbonates of acyclic vinyl diols react with nucleophiles in the presence of a palladium complex as a catalyst under neutral conditions to afford alkylated (E)-allylic alcohols with highly regio-, and diastereoselectivity. This reaction represents an efficient 1,3-chirality transfer method.

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页码：1139 / 1140

页数：2

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