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SILYLAMINES IN ORGANIC-SYNTHESIS - FACILE SYNTHETIC ROUTES TO UNSATURATED PROTECTED PRIMARY AMINES

被引：19
作者：
CORRIU, RJP
HUYNH, V
IQBAL, J
MOREAU, JJE
VERNHET, C
机构：
来源：
TETRAHEDRON | 1992年 / 48卷 / 30期
关键词：
SILYLAMINES; PROPARGYLAMINES; ALPHA-ALLENYLAMINES; N; N-BIS(SILYL)DIENAMINES;
D O I：
10.1016/S0040-4020(01)88215-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines. These are shown to be useful precursors of various unsaturated protected primary amines. Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and alpha-allenic amines.
引用
收藏
页码：6231 / 6244
页数：14
相关论文
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