O-17 NMR-STUDIES OF N-NITROSAMINES

被引:8
作者
CERIONI, G
GIUMANINI, AG
VERARDO, G
DAHN, H
机构
[1] UNIV UDINE,DIPARTIMENTO SCI & TECNOL CHIM,I-33100 UDINE,ITALY
[2] UNIV LAUSANNE,INST CHIM ORGAN,CH-1005 LAUSANNE,SWITZERLAND
关键词
NATURAL ABUNDANCE; O-17; NMR; N-NITROSAMINES; HAMMETT CORRELATION;
D O I
10.1002/mrc.1260320110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Natural abundance O-17 NMR data for seven aliphatic, nine cyclic and thirteen aromatic N-nitrosamines, recorded at room temperature in acetonitrile, are reported. Differences in chemical shifts among and within the three groups are discussed in terms of electronic and steric effects. The sigma(+) value for the N-nitrosamine group was estimated. A comparison between amides and N-nitrosamines was made.
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页码:46 / 50
页数:5
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