SOLVATION AS CAUSE FOR SLOWER RATES OF CYANIDE AND THIOL ANION CATALYZED PROTON ABSTRACTION FROM CARBON COMPARED TO OXY ANIONS OF SAME BASICITY

被引:21
作者
POHL, ER [1 ]
HUPE, DJ [1 ]
机构
[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109
关键词
D O I
10.1021/ja00494a018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:8130 / 8133
页数:4
相关论文
共 16 条
[1]  
AHRENS ML, 1970, BERICH BUNSEN GESELL, V74, P380
[2]   KINETIC HYDROGEN ISOTOPE EFFECTS IN IONIZATION OF SOME NITROPARAFFINS [J].
BELL, RP ;
GOODALL, DM .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 294 (1438) :273-&
[3]  
BELL RP, 1973, PROTON CHEM, P203
[4]   KINETIC ISOTOPE EFFECTS AS GUIDES TO TRANSITION-STATE STRUCTURES IN DEPROTONATION REACTIONS [J].
BORDWELL, FG ;
BOYLE, WJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (02) :512-&
[5]   ON SLOPE OF FREE ENERGY PLOTS IN CHEMICAL KINETICS [J].
COHEN, AO ;
MARCUS, RA .
JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) :4249-&
[6]   TISSUE SULFHYDRYL GROUPS [J].
ELLMAN, GL .
ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1959, 82 (01) :70-77
[7]  
HAPWORTH A, 1930, J CHEM SOC, P1976
[8]   NONLINEAR STRUCTURE-REACTIVITY CORRELATIONS - ACYL TRANSFER BETWEEN SULFUR AND OXYGEN NUCLEOPHILES [J].
HUPE, DJ ;
JENCKS, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) :451-464
[9]   EFFECT OF SOLVATION ON BRONSTED BETA-VALUES FOR PROTON-TRANSFER REACTIONS [J].
HUPE, DJ ;
WU, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (23) :7653-7659
[10]   THERMODYNAMICS OF METAL-CYANIDE COORDINATION .1. PK, DELTAHO, AND DELTASO VALUES AS A FUNCTION OF TEMPERATURE FOR HYDROCYANIC ACID DISSOCIATION IN AQUEOUS SOLUTION [J].
IZATT, RM ;
CHRISTENSEN, JJ ;
PACK, RT ;
BENCH, R .
INORGANIC CHEMISTRY, 1962, 1 (04) :828-&